Day 1: Guiyang

Guiyang is the capital city of Guizhou province and the starting point of your trip. You can explore the city's cultural and historical attractions such as Jiaxiu Tower, Qingyan Ancient Town, and the Guizhou Provincial Museum.

Day 2: Huangguoshu Waterfall

Located about 130 kilometers from Guiyang, Huangguoshu Waterfall is the largest waterfall in Asia and one of the most popular tourist attractions in Guizhou. You can take a bus or hire a car to get there and spend the day hiking, admiring the waterfall, and exploring the surrounding national park.

Day 3: Xijiang Miao Village

Xijiang Miao Village is the largest Miao ethnic village in China and is famous for its traditional architecture, customs, and festivals. It is located about 170 kilometers from Huangguoshu Waterfall and can be reached by bus or car. Spend the day walking in the village, learning about the Miao culture, and enjoying the local food and drinks.

Day 4: Fanjing Mountain

Fanjing Mountain is a UNESCO World Heritage Site and the highest peak in Guizhou province. It is home to rare and endemic species of flora and fauna, such as the golden monkey and the Guizhou snub-nosed monkey. You can take a bus or hire a car to Tongren city and then hike up to the mountain. The hike takes about 6-8 hours, and you can spend the night in a mountain lodge.

Day 5: Zhenyuan Ancient Town

Zhenyuan Ancient Town is a well-preserved ancient town located about 200 kilometers from Fanjing Mountain. It has a history of more than 2,000 years and is famous for its winding streets, ancient buildings, and beautiful scenery. You can take a bus or hire a car to get there and spend the day exploring the town and its attractions such as Wuyang River and Zhusheng Bridge.

In conclusion, this 5-day itinerary covers some of the best tourist attractions in Guizhou province. You can experience the rich culture, history, and natural beauty of the region while enjoying the local food and drinks. Remember to pack comfortable clothes and shoes, as well as sunscreen and insect repellent. Have a great trip!